Preprint / Version 1

Proof of NH2-MWCNT/HRB nanocomposite as a revolutionary material in spacecraft: non- compromising improver in mass ratio and radiation shielding, and a growing in relevance component in the aerospace and scientific community.

##article.authors##

  • Neal Lobo Chatrabhuj Narsee School
  • Riddhim Garg
  • Ebenezer Isaac
  • Rayyan Sayed

DOI:

https://doi.org/10.58445/rars.973

Keywords:

NH2-MWCNT/HRB, spacecraft, space radiation shielding

Abstract

Effective space radiation shielding is extremely crucial to the well-being of astronauts, to prevent them from serious health implications, such as immunity dysfunction, carcinogenesis, skin injuries, and more [1]. Spacecraft components are currently manufactured from aluminum owing to their cost-effectiveness and low weight. However, Aluminum performs poorly in providing effective spacecraft shielding against radiation [2]. Long and pure fibers of CNTs cannot be produced by typically used Chemical Vapor Deposition due to the limited amount of supply of catalyst that can be provided [3]. CNTs are polymerized with different materials such as epoxy resin to obtain long fibers. But in this process some properties like thermal radiation shielding capacity are compromised, which becomes a major concern for aerospace engineers [4]. Implementing the novel technology that Tuball has developed using the CNTs and using NH2 - MWCNT/HRB nanocomposite as a radiation-shielding material in spacecraft, may prove more effective than present materials in missions with long-term exposure to thermal radiation. Its characteristic of being a low atomic number polymer will offer significant mass savings without compromising on any other mechanical properties like tensile strength. Keywords: NH2- MWCNT/HRB nanocomposite, Radiation shielding, Thermal expansion, Tensile strength, Carbon nanotubes (CNTs).

References

J.C. Chancellor, G.B. Scott, J.F. Sutton, “Space Radiation: The Number One Risk to Astronaut Health beyond Low Earth Orbit,” Life (Basel), 4(3), pp. 491- 510, Sep 2014.

Z. Li, S. Nambiar, W. Zheng, J.T.W. Yeow, “PDMS/single-walled carbon nanotube composite for proton radiation shielding in space applications,” Materials Letters, 108(2013), pp. 79-83.

N. M. Mubarak, E. C. Abdullah, N. S. Jayakumar, and J. N. Sahu, “An overview on methods for the production of carbon nanotubes,” Journal of Industrial and Engineering Chemistry, vol. 20, no. 4, pp. 1186–1197, Jul. 2014, doi: https:// doi.org/10.1016/j.jiec.2013.09.001.

V. K. Srivastava, “Modelling and mechanical performance of carbon nanotube/epoxy resin composites,” Materials & Design, vol. 39, pp. 432–436, Aug. 2012, doi: https://doi.org/10.1016/j.matdes.2012.02.039

Huynh, C.P., et al., Evolution of directly-spinnable carbon nanotube growth by recycling analysis. Carbon (Inpress), 2011.

J.-H. Cha, W.-H. Jang, S. K. Sarath Kumar, J.-E. Noh, J.-S. Choi, and C.-G. Kim, “Functionalized multi-walled carbon nanotubes/hydrogen-rich benzoxazine nanocomposites for cosmic radiation shielding with enhanced mechanical properties and space environment resistance,” Composites Science and Technology, vol. 228, p. 109634, Sep. 2022, doi: https://doi.org/10.1016/j.compscitech.2022.109634.

N. Khandoker, S. C. Hawkins, R. Ibrahim, C. P. Huynh, and F. Deng, “Tensile Strength of Spinnable Multiwall Carbon Nanotubes,” Procedia Engineering, vol. 10, pp. 2572–2578, Jan. 2011, doi: https://doi.org/10.1016/j.proeng.2011.04.424.

D. Iguchi, S. Ohashi, G.J.E. Abarro, X. Yin, S. Winroth, C. Scott, M. Gleydura, L. Jin, N. Kanagasegar, C. Lo, C.R. Arza, P. Froimowicz, H. Ishida, Development of hydrogen-rich benzoxazine resins with low polymerization temperature for space radiation shielding, ACS Omega 3 (2018) 11569–11581, https://doi.org/10.1021/ acsomega.8b01297.

Chi P. Huynh and S.C. Hawkins, Understanding the synthesis of directly spinnable carbon nanotube forests. Carbon 2010. 4 8: p. 1105-1115.

Yu, M.-F., et al., Strength and Breaking Mechanism of Multiwalled Carbon Nanotubes Under Tensile Load. Science, 2000. 287(5453): p. 637-640.

Cleveland, J.P., et al., A nondestructive method for determining the spring constant of cantilevers for scanning force microscopy. Rev. Sci. Instrum. , 1993. 64(2): p. 403-405.

Sadera, J.E., J.W.M. Chon, and P. Mulvaney, Calibration of rectangular atomic force microscope cantilevers. Review of Scientific Instruments 1999. 70(10).

M. Kaleemullah, S. U. Khan, and J.-K. Kim, “Effect of surfactant treatment on thermal stability and mechanical properties of CNT/polybenzoxazine nanocomposites,” Composites Science and Technology, vol. 72, no. 16, pp. 1968–1976, Nov. 2012, doi: https://doi.org/10.1016/j.compscitech.2012.08.020.

Deng, F., T. Ogasawara, and N. Takeda. Microscopic dynamic observaƟon and experimental characterizaƟon of carbon nanotubes Poly ether ether ketone composites. in TwelŌh US-Japan conference on composite materials.

Thostenson E, Ren Z, Chou TW. Advances in the science and technology of carbon nanotubes and their composites: a review. Compos Sci Technol 2001;61:1899–912.

Xie XL, Mai YW, Zhou XP. Dispersion and alignment of carbon nanotubes in polymer matrix: a review. Mater Sci Eng: R: Rep 2005;49:89–112.

Thostenson ET, Lee CY, Chou TW. Nanocomposites in context. Compos Sci Technol 2005;65:491– 516.

Shalin RE. Epoxy matrices polymer matrix composites. London: Chapman & Hall; 1995. 11– 34.

Rosato DV, Rosato MG, Rosato DV. Epoxy plasƟc concise encyclopedia of plasƟcs, vol. 237 Boston: Kluwer Academic Publishers; 2000.

L. Dumas, L. Bonnaud, and P. Dubois, “Chapter 38 - Polybenzoxazine Nanocomposites: Case Study of Carbon Nanotubes,” ScienceDirect, Jan. 01, 2017.

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Posted

2024-02-17